Growth and dissolution of NaO2 in an ether-based electrolyte as the discharge product in the Na-O2 cell.

نویسندگان

  • Iain M Aldous
  • Laurence J Hardwick
چکیده

The deposition and dissolution of sodium superoxide (NaO2) was investigated by atomic force microscopy. Rectangular prisms consisting of 8 smaller sub-structures grew from NaO2 platelets, when discharged in 0.5 M NaClO4, diethylene glycol dimethyl ether on highly ordered pyrolytic graphite. During oxidation the 8 sub-structures are conserved. Ring-like structures of Na2CO3 of 200 nm diameter remain at the end of oxidation.

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عنوان ژورنال:
  • Chemical communications

دوره 54 28  شماره 

صفحات  -

تاریخ انتشار 2018